1148148-01-9 (2-二环己基膦-3,6-二甲氧基-2',4',6'-三异丙基-1,1'-苯联)[2-(2-氨基乙苯基苯)]氯化钯(II)

库存 ：100g

英文名 ：BrettPhos Pd G1

CAS号 ：1148148-01-9

保质期 ：6个月

供应商 ：武汉膦配巴

保存条件 ：密封避光冷藏

规格 ：每克

1148148-01-9
BrettPhos PdG1, Methyl t-Butyl Ether Adduct
Synonym: (BrettPhos) palladium(II) phenethylamine chloride, 
BrettPhos Palladacycle, BrettPhos precatalyst, 
Chloro[2-(dicyclohexylphosphino)-3,6-dimethoxy-2′,4′, 6′-triisopropyl-1,1′-biphenyl][2-(2-aminoethyl)phenyl]palladium(II)

CAS 1148148-01-9
Formula: C43H63ClNO2PPd
Formula Weight: 798.81 g/mol
Appearance (Color) White to Light Yellow
assay  97%
mp  198-204 °C
Caution : air sensitive, refrigeration
shelf life :12 month 
Supplier: LPBchem-Benjamin

ISO9001 Manufacturer 
Standard laboratory 
ligands catalysts synthesis pharmaceutical compounds electronic intermediates

Related Categories    
Buchwald 1st Generation Palladacycles, Buchwald Ligands and Complexes, Catalysis and Inorganic Chemistry, Chemical Synthesis, Cross-Coupling,
Homogeneous Pd Catalysts, Other Palladacycle Coupling Catalysts, Palladium Catalysts

General description
BrettPhos Pd G1 is a Buchwald first generation (G1) palladacycle precatalyst that can be used in cross-coupling reactions for the formation of C-C, C–N, C–O, C–F, C–CF3, and C–S bonds. The formation of the active Pd(0) species in the G1 precatalyst is easy to generate, requiring merely a deprotonation with a base. The resulting catalyst is very active, even at temperatures down to ?40 °C, and can be used in a variety of cross-coupling protocols.

Application
Catalyst for:
-C,N-cross coupling of unprotected 3-halo-2-aminopyridines with primary and secondary amines
-Amination reaction
- N-arylation of aminophenols